Electrode Tortuosity Tester & Separator Ion Conductivity Tester

Characteristic

1. Calculate the tortuosity of the electrode by testing the EIS of the battery with symmetrical electrodes.

2. Simple assembly, automated testing and analysis, simplified operating steps, and improved testing efficiency.

3. Four-channel synchronous test.

4. McMullin Number and Tortuosity Measurement

Applications

1. Electrode tortuosity test

2. Separator ion conductivity test

Description

1. Creative Solution One

1.1 Creative Solution:

1) Calculate the MacMullin number of the electrode by testing the EIS of the symmetric cell.
2) Simplify assembly, automate testing and analysis processes, streamline operation steps,and enhance testing efficiency.
3) Synchronous testing across four channels.

1.2 Testing Principle:

Application Cases

Case 1. Different compaction density of cathode electrodes

Summary:

1) The consistency of ElS testing for symmetric battery of electrodes is generally good.
2) Within a certain range of compaction density, as the compaction increases, the ionic resistance/MacMullin numb also increases.

Case 2. Different compaction density of anode electrodes

Summary:

1) The consistency of ElS testing for symmetric battery of electrodes is generally good.
2) Within a certain range of compaction density, as the compaction increases, the ionic resistance/MacMullin numb also increases.

Case 3. The correlation between electrode tortuosity and electrochemical performance(Gr anode electrodes of different thicknesses)

Summary:

1) As the thickness of the electrode increases, its tortuosity also increases, However, the rate performance of the battery decreases with increasing thickness.
2) This indicates that the rate performance of the battery decreases with increasing tortuosity. There is a certain correlation between electrode tortuosity and rate performance of battery.

Case 4. Different coated separators(Ionic conductivity testing of four different coated separators)

Summary:

1) Test the EIS of 1-4 layers of separators to obtain R1, R2, R3, R4.
2) Plot a curve with the number of separator layers as the x-axis and separator resistance as the y-axis. Calculate the slope and linear fitting degree of the curve, with the linear fitting degree ≥0.99.
3) Calculate the separator ionic conductivity according to the formula.

Case 5. Correlation between the tortuosity of the electrode and its electrochemical performance in different electrolytes

Summary:

1) MacMullin number Ranking: Formula 2＜ Formula 1＜ Formula 3
2) Capacity retenuation Ranking(10C): Formula 2(93.92%) ＞ Formula 1(90.55%)＞ Formula 3(89%)

Case 6.  Tortuosity & Wettability of LFP Cathodes with Different Compaction Densities

Summary:

1) Electrode with poorer wettability exhibit greater tortuosity.
2) As compaction density increases, electrolyte absorption declines, hindering permeation and lithium-ion migration, which elevates ion transport resistance and electrode tortuosity.